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Quantum mechanics: FirstPrinciples Primer

Writer's picture: FirstPrinciplesFirstPrinciples

Explore the origins, key principles, and profound implications of quantum mechanics, one of the most successful theories in the history of physics.


A coin flip is often used as a symbol of pure chance, a simple event with two possible outcomes. But if you knew all the details—the force of the flip, the air resistance, the surface it lands on—you could, in principle, predict with certainty which side the coin would land on. That’s how the classical world works: given enough information, outcomes are fully determined.


But in the quantum world, things aren’t so simple. Quantum mechanics describes nature at its smallest scales—a universe where particles exist in many states at once, where outcomes are not set in stone but rather emerge from probabilities, and where observation itself seems to shape reality. This fundamental theory has revolutionized our understanding of the universe and enabled our modern technologies.


A new kind of universe: Classical vs. quantum

For centuries, classical physics—governed by Newton’s laws—described the cosmos as a deterministic system. In this clockwork world, knowing the initial conditions of a system meant you could, in principle, predict its future. Whether it was the orbit of a planet or the trajectory of a projectile, everything followed definite laws with predictable outcomes.


But as scientists began to zoom in on the atomic scale, this neat picture started to unravel, with particles behaving in defiance of our everyday experiences. Instead of behaving like miniature billiard balls with definite positions and velocities, particles appeared to exist in multiple possible states simultaneously—a phenomenon known as superposition. Rather than having fixed, predictable trajectories, their behavior appeared to be dictated by probability.


The fundamental shift from the classical deterministic point of view to the quantum probabilistic one meant that the exact outcomes of measurements suddenly became uncertain. Instead, what quantum mechanics provides us with is a very precise way to predict the probabilities of outcomes. In other words, while classical physics predicts for certain whether the billiard ball will sink, quantum mechanics only predicts the probability that it does. This shift from certainty to probability required a series of groundbreaking experiments and conceptual leaps to gain acceptance in the scientific community.


The spark of a revolution: A brief history of quantum mechanics

At the turn of the 20th century, there were several theoretical and experimental advances that ultimately led to the development of quantum physics as we know it today.


Max Planck in a suit with a bowtie sits against a dark background, holding a small book with both hands. Serious expression. Black and white.
Max Planck

The first breakthrough came in 1900 when Max Planck tackled the problem of black-body radiation, which concerns the emission of electromagnetic radiation by objects with a temperature above absolute zero. Classical physics predicted that the amount of energy emitted would be infinite, which is impossible. To resolve this, Planck proposed that energy is discretized and emitted in finite packets, now known as quanta (though even Planck himself initially viewed this as a mathematical convenience, rather than a fundamental change in physics).


In 1905, Albert Einstein built on this idea to explain the photoelectric effect, a phenomenon in which light strikes a material (usually a metal) and ejects electrons from its surface. Einstein proposed that light must be quantized as discrete packets of energy, later named “photons,” and showed that the photon’s energy must exceed certain thresholds for electrons to be emitted. (This was actually the work that won Einstein his Nobel Prize, not his more famous efforts on relativity.)


In 1913, to explain these phenomena, Niels Bohr proposed a theoretical model of the atom where the electrons that orbit around the nucleus can only assume certain specific levels of energy. His theory explained that atoms can only emit or absorb specific discrete amounts of energy at a time, which also explained the emission and absorption spectrum of elements.


Erwin Schrodinger with glasses and a bow tie in a suit looks directly at the camera. Black and white background, serious expression, vintage style.
Erwin Schrödinger

It was Louis de Broglie that extended the wave-particle duality beyond light in 1924 by proposing that electrons could exhibit wave-like properties. This new vision of the quantum world finally culminated in 1926 with the formulation by Erwin Schrödinger of the famous equation now named in his honor.


Together with contributions from Werner Heisenberg, Paul Dirac, Max Born, and others, these breakthroughs upended classical ideas and laid the foundation for the modern quantum world, where uncertainty and probability are central.


Decoding the quantum world: What is quantum mechanics?

At its core, quantum mechanics is a theoretical framework that explains how matter and energy behave at atomic and subatomic scales. At those microscopic scales, particles are described by the wave function (Ψ), a mathematical description that encapsulates all possible states and their probabilities. This means systems are no longer described by their exact trajectories, but rather by the set of all their possible configurations and their respective probabilities.

It is within this framework that the concept of superposition arises. Superposition refers to the fact that, until a measurement is made, it is impossible to predict which of the possible configurations will occur. Only when we perform a measurement does the wave function “collapse” into one specific outcome. Although the process by which the wave function collapses is still hotly debated by the community, the evolution of the wave function is very precisely understood. It is encapsulated in the Schrödinger equation:

Schrödinger equation: iħ(∂/∂t)|Ψ⟩=Ĥ|Ψ⟩, showing quantum mechanics concept in black text on white background.

The Schrödinger equation describes how quantum systems evolve over time. Here, Ψ is the wave function of the system, H^ represents the Hamiltonian operator (which represents the total energy of the system), ℏ is the reduced Planck constant, and i is the imaginary number.


While its mathematical details can be complex, it serves a similar conceptual role to Newton’s laws in classical physics: it lets us calculate how quantum states change. The key difference is that it tracks probabilities rather than definite trajectories.


Embracing uncertainty: The Copenhagen interpretation

Due to the counterintuitive nature of quantum mechanics, various interpretations have emerged to explain its deeper meaning and implications. Among them, the Copenhagen interpretation is the most widely taught. Developed primarily by Bohr and Heisenberg in the 1920s, it asserts that quantum mechanics does not describe an objective reality, but instead provides a framework to conveniently describe phenomena.


According to the Copenhagen interpretation, a quantum system remains in a superposition of states until it is observed. The act of measurement forces the wave function to collapse into a definite state from among its possible values. This ‘collapse’ represents one of quantum mechanics’ puzzling aspects—the transition from multiple simultaneous possibilities to a single reality. The interpretation doesn’t specify precisely how or why this occurs, only that it does so when a quantum system interacts with a measuring apparatus. This idea—that the observer plays a crucial role in shaping reality—is a radical departure from the detached perspective of classical physics, challenging our intuitions about objective existence.


A window into the quantum world: The double-slit experiment

Diagram showing an electron beam gun emitting electrons through a double-slit, creating an interference pattern on the screen, representing the double slit experiment.
An illustration of the double-slit experiment (Credit: Wikimedia)

Perhaps no experiment better illustrates the bizarre nature of quantum mechanics than the famous double-slit experiment. Imagine directing a beam of particles at a barrier with two narrow slits, then observing the pattern that appears on a screen behind the barrier. Classical intuition suggests that particles should pass through one slit or the other, forming two distinct clusters.


Instead, the screen displays an interference pattern—a series of bright and dark bands that signal wave-like behavior. This result implies that each particle behaves as if it passes through both slits at once, interfering with itself.


However, if a detector is placed to observe which slit the particle travels through, the interference pattern vanishes, and the particles behave as individual, classical entities, forming two separate clusters. This experiment vividly illustrates wave-particle duality and shows how the act of observation alters the behavior of a quantum system, a concept that remains central to quantum mechanics.


Beyond Copenhagen: Alternative interpretations

A person walks on a floating path through a cosmic tunnel. Surrounding orbs display vivid scenes, suggesting a journey through space and time, representing the many-worlds interpretation.
Artistic depiction of many-worlds interpretation (Credit: DALL-E)

The Copenhagen interpretation is not the only way to make sense of quantum phenomena. The many-worlds interpretation, proposed by Hugh Everett III, rejects wave function collapse and instead posits that all possible outcomes of quantum measurements occur, each in its own separate branch of reality. David Bohm’s pilot wave theory preserves the notion of determinism by proposing that particles have definite positions at all times, guided by a real wave function that evolves according to Schrödinger’s equation.


Other approaches include the quantum Bayesian (QBism) interpretation, which treats the wave function as a representation of an observer’s subjective knowledge rather than a physical entity, and consistent histories, which attempts to describe quantum systems without reference to measurement or observers. While these interpretations make the same experimental predictions as the Copenhagen interpretation, they offer different philosophical perspectives on the nature of reality.


The quantum toolbox: Technologies born from quantum ideas

While quantum mechanics might seem abstract, its practical applications permeate our daily lives. Modern electronics depend fundamentally on quantum mechanical principles. Transistors and integrated circuits exploit quantum tunneling, where particles traverse seemingly insurmountable energy barriers. This phenomenon, combined with precise manipulation of electron energy levels in semiconductors, creates the logic gates and memory storage powering our digital world.


MRI scan of a human brain, showing detailed gray and white matter. Black background emphasizes the intricate patterns of the brain.
MRI of a human brain (Credit: Wikimedia)

Lasers operate through stimulated emission, where excited atoms release photons in perfect synchronization. The resulting focused beams have transformed medicine and manufacturing as precise cutting and welding tools. MRI machines provide another example from medicine, leveraging the quantum property of spin to generate detailed internal body images. By manipulating the spin states of hydrogen nuclei with magnetic fields, these devices distinguish between tissue types with remarkable precision.


Quantum technologies have also played a role in sustainability efforts in recent years. LED lighting achieves exceptional efficiency through quantum transitions in semiconductor materials. When electrons jump between discrete energy levels, they emit photons of specific wavelengths, enabling significant energy savings and precise color control. Solar cells provide another example; they convert sunlight to electricity through the photoelectric effect.


Quantum cryptography is one of the more commonly cited applications of quantum mechanics. By creating communication channels where attempted interception necessarily disturbs the quantum states, it immediately reveals eavesdroppers, thereby offering more secure communication.


The next generation of quantum technologies promises even more remarkable capabilities. Utilizing quantum bits or “qubits” that exist in multiple states simultaneously, quantum computers could solve certain complex problems exponentially faster than traditional computers. Once current engineering challenges are overcome, they could revolutionize drug discovery and materials science. Quantum sensors might detect everything from hidden oil deposits to distant exoplanets with unprecedented precision, opening new frontiers in exploration.


Unanswered mysteries: The quest for quantum gravity and more

Even after more than a century of discovery, quantum mechanics continues to challenge us with profound questions. The measurement problem—how and why quantum superpositions collapse into definite states—remains hotly debated. While quantum decoherence provides some insights into how interactions with the environment can erase quantum behavior, the fundamental mechanism remains one of quantum theory’s deepest mysteries.


One of the most formidable challenges in all of physics is the quest for quantum gravity, a theory unifying quantum mechanics with general relativity, which describes gravity at large scales. Several established efforts aim to bridge this divide. String theory proposes that fundamental particles emerge from tiny, one-dimensional strings vibrating in different states. Loop quantum gravity, meanwhile, suggests that spacetime itself is quantized. The holographic principle and the AdS/CFT correspondence offer another perspective, suggesting that gravity in a higher-dimensional space can be described by a lower-dimensional quantum field theory, potentially providing a framework for quantum gravity.


While quantum mechanics itself is exceptionally well-verified, these frontier areas represent active research where scientific consensus hasn’t yet formed. As we probe deeper into quantum phenomena, new questions drive research at scientific institutions around the world.


Charting a new course: Embracing the quantum frontier

Quantum mechanics has revolutionized our understanding of nature and enabled technological advances—such as the precision of smartphones or the focused beam of a laser—that would seem magical to scientists of a century ago. These technologies represent quantum principles in action—principles that once challenged our deepest intuitions about reality.


Quantum mechanics marked a paradigm shift, transforming a predictable, clockwork universe into a dynamic realm where probability reigns. As we continue exploring its implications, quantum mechanics serves as a reminder that the universe is far more fascinating than our classical intuitions suggest.


This article was created with the assistance of artificial intelligence and thoroughly edited by FirstPrinciples staff and scientific advisors.

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iStock-1357123095.jpg

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